Warning: Endgame spoilers begin right away. See the movie first! 
Natlianovna Romanoff, better known in the U.S. as Natasha Romanoff, Black Widow, Avenger, Agent of SHIELD, and former KGB Assassin. These are the only known occupations of this founding member of the Avengers.
Romanoff’s Early Life
Born in 1984s Soviet Russia, Natasha’s early life remains a relative mystery. It is known she was recruited into the KGBs Red Room Academy, where she received training in spycraft, including combat with and without weapons.
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According to leaked SHIELD/HYDRA documents, leaked by Agent Romanoff herself during the fall of SHIELD and the destruction of the Triskelion, the late Director of SHIELD (Nicholas J. Fury) took notice of the master assassin in the mid-late 1990s. At this point, Agent Clint Barton was dispatched to locate and terminate Natasha, code-named Black Widow. Agent Barton persuaded Director Fury to recruit and facilitate her defection from the Soviet Union.
Code Name Black Widow as an Avenger
Black Widow’s activities pre-defection paint her as a clear enemy of the U.S., but her loyalty post-defection clouds the initial analysis. Her membership among the Avengers — indeed — her presence as a Founder of the group of heroes, solidify her status as an ally for most.
Romanoff was instrumental in the destruction of SHIELD and exposure of HYDRA. She was a part of the Avenger’s failed counter-operation to stop Ultron’s destruction of Sokovia, and as a result, an initial signer of the Sokovia Accords, regulating the activities of so called “enhanced” individuals, primarily the Avengers themselves.
While obeying the new Accords and helping track down and stop the illegal activities of Steve Rogers/Captain America, Romanoff broke rank and betrayed the task force, ultimately becoming a fugitive, disappearing from intelligence agency sight.
While on the run, the Black Widow continued vigilante operations with Captain America, resurfacing in Wakanda during the first battle with the alien Thanos. For the next five years after The Decimation, Romanoff became the leader of what remained of the Avengers, no longer counted as a fugitive.
Black Widow Post Snap – AKA The Decimation
Finally, according to sources close to the Avengers, during the successful mission to return The Decimated, Natasha Romanoff sacrificed herself on an alien planet, in a time before our own, in order to obtain a necessary piece of equipment to reverse the decimation.
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The Black Widow was not able to fight in the Battle of the Returned at the destroyed Avengers facility. Romanoff is survived only by her team of heroes.
A memorial service is to be scheduled in the days following the private funeral of her fellow Avenger Tony Stark.
RIP Natalia Alianovna Romanoff, 1984-April 26, 2023/2014.
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